Use in Unsaturated Oil Hydrogenation
Introduction
It has long been recognized that saturated fats
tend to increase the level of the "bad" LDL (low-density lipoprotein)
cholesterol. An elevated LDL Cholesterol increases the risk of developing
coronary heart disease.Monounsaturated (having one double bond in their
molecules) and polyunsaturated fats (having two or more double bonds in their
molecules) found primarily in vegetable oils tend to lower "bad" LDL
cholesterol.
Way back in the 1950s it was recognized
that vegetable oils could be substituted for animal fats such as in butter, by
making a product we know as margarine. Vegetable oils which contain more
unsaturated fatty acids are liquids while saturated fatty acids are solids. But
how do you convert an oil into a solid? It is here that hydrogen comes in,
through a process known as hydrogenation.
The Hydrogenation Reaction
Unsaturated fatty acids may be converted to
saturated fatty acids by the relatively simple hydrogenation reaction. Recall
that the addition of hydrogen to an alkene (unsaturated) results in an alkane
(saturated).
A simple hydrogenation reaction is:
H2C=CH2 + H2 ---> CH3CH3
Alkene plus hydrogen yields an alkane.
Apart from making margarine, which is
healthier than most oils, saturated or unsaturated, hydrogen is also used to
manufacture trans-fat through the process of hydrogenation, which, although used
a lot in food processing, is bad for health as they
increase the amount of bad LDL cholesterol and lower good HDL cholesterol in
the body.
Hydrogen plants and hydrogen
generators are common in facilities where hydrogenated vegetable oil is
manufactured, as it provides cost-efficiency, saves time and also provides ease
of access.
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